Microwave-assisted solvothermal synthesis of zirconium oxide based metal-organic frameworks.
نویسندگان
چکیده
Zirconium oxide based Metal-Organic Frameworks were synthesised using a rapid and efficient microwave-assisted solvothermal method that produced purer phases and higher quality crystalline products in significantly (>95%) less time than the conventional heating method. A new amino-functionalised analogue has been synthesised exclusively using this microwave-assisted methodology.
منابع مشابه
Highly crystalline MOF-based materials grown on electrospun nanofibers.
Supported Metal Organic Frameworks (MOFs) with a high specific surface area are of great interest for applications in gas storage, separation, sensing, and catalysis. In the present work we report the synthesis of a novel composite architecture of MOF materials supported on a flexible mat of electrospun nanofibers. The system, based on three-dimensional interwoven nanofibers, was designed by us...
متن کاملResin-assisted solvothermal synthesis of metal-organic frameworks.
Transition metal-exchanged polymer resin beads have been used as a heterogeneous controlled-release source of metal cations in high yielding, phase pure solvothermal syntheses of novel transition metal-organic frameworks.
متن کاملSynthesis of metal-organic frameworks: A mini review
−Metal organic frameworks (MOFs) are porous crystalline materials of one-, two-, or three-dimensional networks constructed from metal ions/clusters and multidentate organic linkers via coordination bonding, which are emerging as an important group of materials for energy storage, CO2 adsorption, alkane/alkene separation, and catalysis. To introduce newcomers in chemical engineering discipline t...
متن کاملEfficient microwave assisted synthesis of metal-organic framework UiO-66: optimization and scale up.
A highly efficient and scalable microwave assisted synthesis of zirconium-based metal-organic framework UiO-66 was developed. In order to identify the best conditions for optimizing the process, a wide range of parameters was investigated. The efficiency of the process was evaluated with the aid of four quantitative indicators. The properties of the materials prepared by microwave irradiation w...
متن کاملRecent progress in the synthesis of metal–organic frameworks
Metal-organic frameworks (MOFs) have attracted considerable attention for various applications due to their tunable structure, porosity and functionality. In general, MOFs have been synthesized from isolated metal ions and organic linkers under hydrothermal or solvothermal conditions via one-spot reactions. The emerging precursor approach and kinetically tuned dimensional augmentation strategy ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 49 35 شماره
صفحات -
تاریخ انتشار 2013